بررسی پارامترهای فرآیندی، هم دمای جذب سطحی و سینتیک در فرآیند جذب سطحی تک جزئی ایندول و کینولین از سوخت مدل توسط کربن فعال زیستی سنتز شده از پوست سبز پسته

نوع مقاله : مقاله شیمی

نویسنده

دانشکده مهندسی شیمی، دانشگاه ارومیه، ارومیه، ایران

چکیده

هدف از این پژوهش مطالعه اثرات پارامترهای فرآیندی مختلف نظیر زمان (min 360-0)، دما (ºC40-25)، دوز جاذب (mg60 -30)، غلظت اولیه ترکیب نیتروژنی ایندول و کینولین (ppm250-100) موجود در سوخت نرمال- هپتان در فرآیند نیتروژن‌زدایی جذبی توسط کربن فعال تولید شده با پوست سبز پسته می‌باشد. مدل‌های سینتیکی شبه مرتبه اول و شبه مرتبه دوم به منظور مطالعه سینتیک جذب سطحی استفاده شدند. همچنین، همدماهای جذب سطحی برای ارزیابی داده‌های تعادلی استفاده شدند. تمامی داده‌های آزمایشگاهی با استفاده از دستگاه طیف‌سنجی UV بعد از انجام آزمایش جذب سطحی تحلیل شدند. دریافت شد که جذب سطحی ترکیبات نیتروژنی ایندول و کینولین توسط کربن فعال سنتز شده با پوست سبز پسته بهترین برازش را توسط همدمای لانگمویر برای ترکیب کینولین و ایندول به ترتیب با بیشترین ظرفیت جذب سطحی 05/31 و mg.g-1 76/37 داشت. براساس داده‌های تجربی، مدل شبه مرتبه دوم بهترین برازش را برای ترکیب کینولین و ایندول به ترتیب با رگرسیون خطی (R2) 9961/0 و 9986/0 نشان داد. از مطالعات سینتیکی و همدمای جذب سطحی تایید شد که کربن فعال سنتز شده پتانسیل مناسبی در حذف ترکیبات نیتروژنی دارد.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Investigating Process Parameters, Adsorption Isotherm, and Kinetics of Indole and Quinoline in Single-Component Adsorption Process from Model Fuel by Activated Carbon Synthesized from Green Pistachio Skin

نویسنده [English]

  • Amin Alamdari
Department of Chemical Engineering, Colleg of Engineeringe, Urmia University, Urmia, Iran
چکیده [English]

The aim of this research is to study the effects of various process parameters such as time (0-360 min), temperature (25-40ºC), adsorbent dose (30-60 mg), initial concentration of nitrogenous compounds indole and quinoline (100-250 ppm) present in normal-heptane fuel on the adsorption denitrification process by activated carbon produced with green pistachio skine. Pseudo-first-order and pseudo-second-order kinetic models were used to study adsorption kinetics. Also, adsorption isotherms were used to evaluate equilibrium data. All laboratory data were analyzed using a UV spectrometer after performing the adsorption test. It was found that the adsorption of nitrogenous compounds of indole and quinoline by activated carbon synthesized with pistachio green skin had the best fit with Langmuir isotherm for quinoline and indole with the highest adsorption capacity of 31.05 and 37.76 mg.g-1, respectively. Based on the experimental data, the pseudo-second order model showed the best fit for quinoline and indole with linear regression (R2) of 0.9961 and 0.9986, respectively. From the kinetic and adsorption isotherm studies of adsorption, it was confirmed that the synthesized activated carbon has a good potential for removing nitrogenous compounds.

کلیدواژه‌ها [English]

  • Indole
  • Quinoline
  • Adsorption
  • Denitrogenation
  • Activated carbon
  • Pistachio green skin
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